Will Smith punched Charlize Theron in the face when they first worked together. The actor was preparing to portray legendary boxer Muhammad Ali when he starred alongside the blonde beauty in 2000's "The Legend of Bagger Vance" - and got carried away showing off his fighting skills.

Charlize said: "The first time I worked with him he punched me in the face. He was training for 'Ali.' I encouraged him to show me a couple of moves. I was completely knocked out!"

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